79115-31-4Relevant academic research and scientific papers
Benzaldehyde lyase-catalyzed direct amidation of aldehydes with nitroso compounds
Ayhan, Peruze,Demir, Ayhan S.
supporting information; experimental part, p. 624 - 629 (2011/04/24)
Benzaldehyde lyase from the Pseudomonas fluorescens catalyzes the reaction of aromatic aldehydes with nitroso compounds and furnishes N-arylhydroxamic acids in high yields. Aromatic aldehydes and benzoins are converted into enamine-carbanion-like intermediates prior to their reaction with nitroso compounds. The kinetic resolution of rac-2-hydroxy-1,2-diphenylethanones furnished (S)-benzoins and arylhydroxamic acids with high enantioselectivities and conversions.
Preparation and Properties of N-Arylhydroxamic Acids
Koshy, Vettithara C.,Tandon, Shiv G.
, p. 421 - 423 (2007/10/02)
Thirteen new N-substituted hydroxamic acids were prepared by the acylation of N-arylhydroxylamine with appropriate acid chloride at low temperature in etheral solutions containing a suspension of sodium bicarbonate.The yields range from 40 percent to 90 p
