79120-30-2Relevant academic research and scientific papers
Synthesis of Platinum(II) Alkyl and Aryl Complexes from K2 and Tetraorganotin Compounds in Dimethyl Sulphoxide
Eaborn, Colin,Kundu, Kalipada,Pidcock, Alan
, p. 933 - 938 (1981)
Complexes cis- and cis-(dmso=dimethyl sulphoxide) are readily obtained from K2 and SnMe3R (R=aryl or Me) in dmso at 70-90 deg C.Hydrogen-1 n.m.r. spectra show that the dmso ligands are bound through sulphur in solution an
On the Reductive Elimination of the Biphenyl System from Substituted cis-Bis(phenyl)bis(triphenylphosphane)platinum(II) Compounds
Bayer, Ulrich,Brune, Hans Albert
, p. 226 - 236 (2007/10/02)
The compounds cis- and cis- have been synthesized and studied thermally with respect to the reductive elimination of disubstituted biphenyls.Activation parameters ΔH and ΔS are reported and discussed. - Keywords: Platinum-organic Compounds, Syntheses, Reductive Elimination, Activation Parameters
