79127-02-9Relevant academic research and scientific papers
The 9-Decalyl and Related Cations. VI Solvolysis of Pent-4-enyl p-Nitrobenzenesulfonate in 1,1,1,3,3,3-Hexafluoropropan-2-ol and of 3-(Cyclohex-1'-enyl)propyl p-Nitrobenzenosulfonate in 2,2,2-Trifluoroethanol and 1,1,1,3,3,3-Hexafluoropropan-2-ol
Ferber, Peter H.,Gream, George E.
, p. 1051 - 1061 (2007/10/02)
Kinetic and product studies have established that pent-4-enyl p-nitrobenzenesulfonate undergoes insignificant solvolysis (1.5percent) by the ?-route in 1,1,1,3,3,3-hexafluoropropan-2-ol. ?-Participation to give the perhydroinden-3a-yl (8-hydrindyl)cation during the solvolysis of 3-(cyclohex-1'-enyl)propyl p-nitrobenzenesulfonate, a substituted pent-4-enyl derivative, in fluorinated alcohols is, however, significant.In buffered 2,2,2-trifluoroethanol, it occurs to the extent of 30percent; in buffered and unbuffered 1,1,1,3,3,3-hexafluoropropan-2-ol, the values are 96 and 98percent, respectively.
