79149-54-5

Upstream product

• 62044-37-5 4-cyanophenylacetic acid chloride 
• 62-53-3 aniline 
• 35525-86-1 4-cyano-N,N-dimethylbenzylamine 
• 201230-82-2 carbon monoxide 

Downstream Products

• 79149-04-5 4-Phenylcarbamoylmethyl-thiobenzimidic acid methyl ester 
• 79149-03-4 4-Phenylcarbamoylmethyl-thiobenzimidic acid methyl ester; hydrochloride 
• 79149-20-5 4-Phenylcarbamoylmethyl-thiobenzimidic acid methyl ester; hydriodide 
• 79149-05-6 4-Amidinophenylessigsaeureanilidhydrochloride 
• 79149-13-6 4-Amidinophenylessigsaeureanilidhydroiodid 
• 110487-21-3 4-[2-(2-Dimethylamino-ethylsulfanyl)-quinolin-3-yl]-benzonitrile 
• 79149-41-0 N-Phenyl-2-(4-thiocarbamoyl-phenyl)-acetamide 
• 85274-84-6 2-chloro-3-(4-cyanophenyl)quinoline 

Relevant academic research and scientific papers

Palladium-catalyzed carbonylation of benzylic ammonium salts to amides and esters: Via C-N bond activation

An efficient palladium-catalyzed carbonylation reaction of readily available quaternary ammonium salts with CO is reported for the first time to afford arylacetamides and arylacetic acid esters via benzylic C-N bond cleavage. This protocol features mild reaction conditions under atmospheric pressure of CO, a redox-neutral process without an additional oxidant, and a broad substrate scope for various kinds of amines, alcohols and phenols.