79150-76-8Relevant academic research and scientific papers
Catalytic reaction of methyl diazoacetate with silylated enynes
Shapiro, E. A.,Kalinin, A. V.,Platonov, D. N.,Nefedov, O. M.
, p. 1191 - 1195 (1993)
Factors affecting the regioselectivity of the catalytic reaction of methyl diatoacetate with 1-trimethylsilylalkene-1-ynes have been revealed.Conditions for selective cyclopropanation of the double bond in 1-trimethylsilylbut-3-ene-1-yne and 1-trimethylsilyl-3-methylbut-3-ene-1-yne in the presence of Rh2(OAc)4 have been found.
