79157-49-6

Upstream product

• 565-68-4 4-methylpent-1-yn-3-ol 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 308143-64-8 N-benzyl-N'-7-methyl-octa-4,5-dienylurea 
• 265331-24-6 N-(p-tolylsulfonyl)-7-methyl-octa-4,5-dienylamine 
• 79157-53-2 (1-Isopropyl-2,2-dimethoxypropyl)-p-toluolsulfonat 

Relevant academic research and scientific papers

Intramolecular palladium(II)-catalyzed 1,2-addition to allenes

Palladium(II)-catalyzed intramolecular 1,2-additions to allenes substituted with an internal nucleophile have been developed. Carboxylic acids, alcohols, N-substituted amides, and carbamates were used as internal nucleophiles in the palladium-catalyzed re

Terpenes and Terpene Derivatives, XI. - Synthesis and Reductions of β-Santalenone hept-2-yl)-3-penten-2-one>

Starting from cyclopentadiene (2) and 2-butynoic acid (3), and via the acids 5 and 7, the allyl alcohol 9 has been prepared. 9 reacts with the dienol ether 10 to give β-santalenone 11.Reduction of 11 with LiAlH4/AlCl3 yields, depending on the reaction temperature various amounts of hydrocarbons 25, 26, and β-santalenone (1), of the ketone 27 and of the alcohol 28.With NaBH4 the alcohols 28 and 29 have been obtained.