791810-01-0

Upstream product

• 321852-62-4 (3E,7Z)-11-Iodo-3,6,6-trimethyl-undeca-3,7-dien-10-ynal 
• 791810-18-9 (3E,7Z)-11-Iodo-3,6,6-trimethyl-undeca-3,7-dien-10-ynal 
• 35066-34-3 methyl (E)-3-methyl-5-<(2-tetrahydropyranyl)oxy>pent-2-enoate 
• 321852-66-8 (4Z,8E)-11-(tert-Butyl-dimethyl-silanyloxy)-6,6,9-trimethyl-1-trimethylsilanyl-undeca-4,8-dien-1-yne 
• 321852-63-5 7-(tert-butyl-dimethyl-silanyloxy)-2,2,5-trimethyl-hept-4-enoic acid ethyl ester 
• 321852-65-7 7-(tert-butyl-dimethyl-silanyloxy)-2,2,5-trimethyl-hept-4-enal 
• 140176-38-1 5-<(tert-butyldimethylsilyl)oxy>-1-chloro-3-methyl-2(E)-pentene 
• 74854-49-2 methyl 5-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-2-pentynoate 
• 321852-64-6 (E)-5-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-pent-2-enoic acid methyl ester 
• 90708-82-0 5-<(tert-Butyldimethylsilyl)oxy>-3-methyl-2(E)-penten-1-ol 
• 791810-15-6 (4Z,8E)-11-(tetrahydro-2H-pyran-2-yloxy)-6,6,9-trimethyl-1-trimethylsilylundeca-4,8-dien-1-yne 
• 791810-16-7 (4Z,8E)-11-(tetrahydro-2H-pyran-2-yloxy)-6,6,9-trimethylundeca-4,8-dien-1-yne 
• 791810-06-5 methyl (2Z)-3-phenylsulfanyl-5-(tetrahydro-2H-pyran-2-yloxy)pent-2-enoate 
• 791810-09-8 methyl (2E)-7-(tetrahydro-2H-pyran-2-yloxy)-2,2,5-trimethylhept-4-enoate 

Downstream Products

• 791810-02-1 [(3E,7Z)-3,6,6-trimethylcycloundeca-3,7-dien-10-yn-1-yl] 4-nitrobenzoate 
• 791810-04-3 5,5,8-trimethyltricyclo[5.4.0.0^1,8]undeca-3-en-11-one 

Relevant academic research and scientific papers

PtCl2-catalyzed transannular cycloisomerization of 1,5-enynes: A new efficient regio- and stereocontrolled access to tricyclic derivatives

(Chemical Equation Presented) Transannular PtCl2-catalyzed cycloisomerizations open a new route to cyclopropanic tricyclic systems. Ketones A or C were efficiently prepared from the same cycloundec-5-en-1-yne precursor B, depending on the subst

Exploration of radical transannulations inside a cycloundecadienyne

An eleven-membered macrocyclic bromomethyldimethylsilyl propargylic ether has been prepared in order to examine the regioselectivity of a transannular radical process. The vinyl radical intermediate appeared to follow exclusively a 6-(π-endo)endo-trig/7-(π-exo)exo-trig transcyclization course to create a 6,7-bicyclic skeleton.