791813-65-5Relevant academic research and scientific papers
Au(I)-catalyzed efficient synthesis of α-acyloxy-α′-silyl ketones from α-acyloxy-α-alkynylsilanes
Sakaguchi, Kazuhiko,Okada, Takuya,Shinada, Tetsuro,Ohfune, Yasufumi
, p. 25 - 28 (2008/09/17)
The Au(I)-catalyzed novel conversion of α-acyloxy-α-alkynylsilanes to α-acyloxy-α′-silyl ketones is reported. Ph3PAuOTf in dioxane in the presence of 1 equiv of H2O efficiently catalyzed both the [3,3] sigmatropic rearrangement and a
