791845-50-6Relevant academic research and scientific papers
Copper-catalyzed hydroboration of propargyl-functionalized alkynes in water
Da Costa, Jessie S.,Braun, Roger K.,Horn, Pedro A.,Lüdtke, Diogo S.,Moro, Angélica V.
, p. 59935 - 59938 (2016/07/11)
The Cu-catalyzed hydroboration of alkynes in operationally simple and environmentally friendly conditions is reported. The reactions are performed in water, at room temperature, under micellar catalysis. Conditions to form the α or β borylated products se
Di(isopropylprenyl)borane: A new hydroboration reagent for the synthesis of alkyl and alkenyl boronic acids
Kalinin, Alexey V.,Scherer, Stefan,Snieckus, Victor
, p. 3399 - 3404 (2007/10/03)
The best of the old: The new hydroboration reagent 1 combines the selectivity of disiamylborane (2) with the reactivity towards carbonyls of allyl boranes 3. Conventional oxidative workup conditions are avoided, as facile hydrolysis in protic media provides the corresponding boronic acids with up to 99% anti-Markovnikov selectivities. A one-pot hydroboration/ Suzuki-Miyaura protocol adds to the synthetic value of 1.
