79207-99-1

Usage

Structure

An anthraquinone derivative with a hydroxyl and a prop-2-en-1-yloxy group attached to the anthracene structure

Enzyme substrate

Xanthine oxidase

Potential use in cancer therapy

Ability to induce cell death in cancer cells
Potential anti-inflammatory properties
Potential antioxidant properties
Versatile compound with potential applications in various fields of research and industry.

Upstream product

• 79207-97-9 1,4-bis(prop-2'-enyloxy)-9,10-anthraquinone 
• 81-64-1 1,4-dihydroxy-9,10-anthracenedione 
• 106-95-6 allyl bromide 

Downstream Products

• 163151-49-3 4-benzyloxy-1-methoxy-2-(prop-1'-enyl)anthraquinone 
• 163151-48-2 4-benzyloxy-1-methoxy-2-(prop-2'-enyl)anthraquinone 
• 163151-50-6 4-benzyloxy-1-methoxy-9,10-dioxo-9,10-dihydroanthracene-2-carbaldehyde 
• 163151-47-1 4-benzyloxy-1-hydroxy-2-(prop-2'-enyl)anthraquinone 
• 130514-62-4 (4'R,5'R)-4-benzyloxy-2-(4',5'-dimethyl-1',3'-dioxolan-2'-yl)-1-methoxyanthraquinone 
• 163151-46-0 1-benzyloxy-4-(prop-2'-enyloxy)anthraquinone 

Relevant academic research and scientific papers

Efficient reductive Claisen rearrangement of prop-2’-enyloxyanthraquinones and 2’-chloroprop-2’-enyloxyanthraquinones with iron powder in ionic liquids

A rapid and selective iron-mediated reductive Claisen rearrangement of various prop-2’-enyloxyanthraquinones and 2’-chloroprop-2’-enyloxyanthraquinones to 1-hydroxy-2-(prop-2’-enyl)anthraquinones and anthrafurandiones is presented. All reactions are carried out in a mixture of ionic liquids, [Bzmim]Cl (1-benzyl-3-methylimidazolium chloride) and [Hmim]BF4 (1-methylimidazolium tetrafluoroborate), in short reaction times (5–35 min). Our study showed that 1-(prop-2’-enyloxy)anthraquinone is more active than 1-(2’-chloroprop-2’-enyloxy)anthraquinone to perform this rearrangement.

Anthracene derivative covalently immobilized on sensing membrane as a fluorescent carrier for water assay

This article describes an optical chemical sensor based on a fluorescent dye 1-allyloxy-4-hydroxyanthracene-9, 10-dione (AHD) with terminal double bond, which is covalently bonded to quartz glass plate surface treated with a silanizing agent to prevent its leakage. The purpose of this work was to characterize and optimize the sensor for determining the water content in the acetone organic solvent. The sensor is resistant to swelling; the membrane possesses relatively long lifetime, short response and recovering time. The reversibility and reproducibility of the sensor are adequate for practical measurements.

Experiments Directed Towards the Synthesis of Anthracyclinones. VI Claisen Rearrangements of 1,4-Bis(prop-2'-enyloxy)anthraquinone

The Claisen rearrangement of 1,4-bis(prop-2'-enyloxy)anthraquinone (1) in N,N-diethylaniline and acetic anhydride has been examined.New products include compounds (3), and (6) and (14) in which a double bond has also migrated.Rearrangement of the compound (3) in o-dichlorobenzene affords the ketone (2), which supports an earlier mechanistic proposal.