79209-38-4Relevant academic research and scientific papers
Transannular Reactions of Cycloalkenes, Cycloalkadienes and Cycloalkatrienes. VIII. The Electrophilic Addition of Pseudohalogenes to Cycloocta-1(Z),5(Z)-diene
Haufe, Guenter,Muehlstaedt, Manfred
, p. 89 - 92 (2007/10/02)
The reaction of cycloocta-1(Z),5(Z)-diene 5 with chlorothiocyanate is described.The main process is the normal anti-addition to produce trans-5-chloro-6-thiocyanato-(Z)-cyclooctene 6.In addition 2,6-dichloro-9-thiabicyclononane 7 and 2,6-dithiocyanato-9-thiabicyclononane 8 are obtained as products of a transannular reaction.
