79233-09-3

Basic information

• Product Name: 2-(3,7-Dimethyl-2,6-octadien-1-yl) 1,4-dimethoxybenzene
• Synonyms: 2-(3,7-Dimethyl-2,6-octadien-1-yl) 1,4-dimethoxybenzene
• CAS NO: 79233-09-3
• Molecular Weight: 274.403
• Mol File: 79233-09-3.mol

Chemical Properties

• CAS DataBase Reference: 2-(3,7-Dimethyl-2,6-octadien-1-yl) 1,4-dimethoxybenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(3,7-Dimethyl-2,6-octadien-1-yl) 1,4-dimethoxybenzene(79233-09-3)
• EPA Substance Registry System: 2-(3,7-Dimethyl-2,6-octadien-1-yl) 1,4-dimethoxybenzene(79233-09-3)

Safety Data

• Hazardous Substances Data: 79233-09-3(Hazardous Substances Data)

Upstream product

• 106-24-1 Geraniol 
• 150-78-7 1,4-dimethoxybezene 
• 83036-59-3 geranyl diisopropyl phosphate 
• 25245-34-5 1-bromo-2,5-dimethoxybenzene 
• 5389-87-7 1-chloro-3,7-dimethylocta-2,6-diene 
• 150-76-5 4-methoxy-phenol 
• 79233-10-6 (E)-2-(3,7-dimethylocta-2,6-dien-1-yl)-4-methoxyphenol 
• 74-88-4 methyl iodide 

Downstream Products

• 79233-07-1 1,4-dimethoxy-2-(3,7-dimethyl-6-phenylthio-octa-3,7-dienyl)benzene 
• 79233-08-2 1,4-dimethoxy-2-(3,7-dimethyl-2,6-bisphenylthio-octa-3,7-dienyl)benzene 
• 50628-18-7 2,6-dimethyl-8-(2,5-dimethoxyphenyl)octa-2,6-dienal 
• 50628-18-7 di-O-methylalliodorin 
• 66397-43-1 8-(2,5-dimethoxyphenyl)-2,6-dimethylocta-2,6-dienol 
• 79233-06-0 6-(2,5-dimethoxyphenyl)-1-isopropenyl-4-methylhex-4-enyl phenyl sulphoxide 
• 66397-43-1 8-(2,5-dimethoxyphenyl)-2,6-dimethylocta-2,6-dienol 
• 50906-59-7 alliodorine EE 

Relevant articles and documents

Microwave-assisted efficient synthesis of alliodorin and (±)- curcuhydroquinone

Terpenoids 1 and 2 have been synthesized from readily available starting materials using Li2CuCl4-catalysed coupling of Grignard reagents with alkyl/aryl bromides and microwave-assisted oxidation of allylic methyl groups, using SeOs

PRENYLATION OF OLEFINS IN NITROMETHANE

The prenylation of isopentenyl and 3,3-dimethylallyl derivatives could be achieved efficiently with dimethyl vinyl carbinol and a variety of acids in nitromethane.Geraniol and isopentenylacetate led to farnesyl derivatives.

AN EFFICIENT REGIO- AND STEREOSPECIFIC ALKENYLATION OF PHENOLIC ETHERS BY PRENYL AND GERANYL DIISOPROPYL PHOSPHATES

Prenyl and geranyl diisopropyl phosphates readily alkenylate a variety of phenolic ethers regio- and stereospecifically without any appreciable side reactions.

Acid-catalysed Intramolecular Cyclization of Geranyl Hydroquinone Derivatives from Cordia alliodora. X-Ray Crystal and Molecular Structure of 1,2,3,3a,4,9,10,10a-Octahydro-5,8-dimethoxy-3,10-dimethyl-3a,9-epoxybenzazulene

The aqueous acid-catalysed intramolecular cyclization of dimethylated alliodorin (2) obtained from the heartwood of Cordia alliodora has been characterized by X-ray analysis as the unusual tetracyclic di-O-methyl hydroquinone title compound (8).A new synthesis of di-O-methylalliodorin (2) from a terminal methylallylic sulphide derivative of 2-geranil-1,4-dimethoxybenzene is described. Crystals of the title compound (8) are monoclinic, space group P21/c, unit cell dimensions a = 14.984(7), b = 5.206(4), c = 20.131(9) Angstroem, β = 99.77(1) deg, Z = 4.The structure was solved by direct methods and refined by least-squares calculations to an R value of 0.078 for 1 832 independent reflections measured on a diffractometer using Cu-Kα radiation.