79236-77-4Relevant academic research and scientific papers
Unexpected oxadi-π-methane rearrangement of β,γ-unsaturated aldehydes
Armesto, Diego,Ortiz, Maria J.,Romano, Santiago,Agarrabeitia, Antonia R.,Gallego, Mar G.,Ramos, Ana
, p. 1459 - 1466 (2007/10/03)
The oxadi-π-methane rearrangement (ODPM) is considered to represent the normal photochemical behavior of β,γ-unsaturated ketones in the triplet excited π,π* state. However, the usual photoreactivity reported for the majority of β,γ-unsaturated aldehydes i
Photochemistry in a Box. Photochemical Reactions of Molecules Entrapped in Crystal Lattices: Mechanistic and Exploratory Organic Photochemistry
Zimmerman, Howard E.,Zuraw, Michael J.
, p. 7974 - 7989 (2007/10/02)
An exploration was made of the photochemical behavior in the crystalline state of a series of molecules we have previously studied in solution.The reactions studied fall into the categories of cyclohexenone rearrangements, reactions of di-?-methane system
Studies on the Scope of the aza-di-?-methane Rearrangement of β,γ-Unsaturated Imines
Armesto, Diego,Langa, Fernando,Martin, Juan-Antonio Fernandez,Perez-Ossorio, Rafael,Horspool, William M.
, p. 743 - 746 (2007/10/02)
The syntheses of imines of 2,2,4,4-tetraphenylbut-3-enal, 3,3-dimethyl-5,5-diphenylpent-4-en-2-one, and 2,2-dimethyl-1,4,4-triphenylbut-3-en-1-one are described.The results of the irradiation of these and of 2,2-dimethyl-4,4-diphenylbut-3-enonitrile and 2
