79238-75-8Relevant academic research and scientific papers
Halides-based electrophiles mediated epoxide ring-opening reactions of α,β-epoxysulfoxides in C6-series : Deoxygenation versus dehydration and an overall 1,2-keto transposition
Barillier, Daniel,Levillain, Jocelyne,Vazeux, Michel
, p. 5413 - 5424 (2007/10/02)
New syntheses of α-thiosubstituted carbonyl compounds with the carbonyl carbon being the one that originally does not carry the sulfoxide group from six-membered ring α,β-epoxysulfoxides and several halides-based electrophiles are described. Mechanistic considerations for deoxygenation as well as dehydration reactions are also discussed. In addition, methodology for achieving 1,2-carbonyl transposition starting with isomerically pure cyclohexenyl sulfides derived from isophorone and cholestan-3-one is briefly reported.
OBTENTION D'UN OXIRANNE PAR ACTION DE L'OZONE SUR UN VINYLSULFURE
Morin, Luc,Barillier, Daniel,Strobel, Marie-Paule,Paquer, Daniel
, p. 2267 - 2268 (2007/10/02)
Ozone reacts with one vinyl sulphide and gives an oxirane; this fact confirms that oxirane is probably an intermediate in course of reactions of ozone with vinyl derivates which give products containing unmodified hydrocarbon chains.
