79240-17-8Relevant academic research and scientific papers
Regio- and Stereoselective Synthesis of Allylic and Homoallylic Alcohols by the Reductive Desulfonylation of Allylic Sulfone Derivatives. Application to the Syntheses of (+/-)-Lavandulol and Isolavandulol
Inomata, Katsuhiko,Igarashi, Susumu,Mohri, Mitsunobu,Yamamoto, Taku,Kinoshita, Hideki,Kotake, Hiroshi
, p. 707 - 710 (2007/10/02)
Regio- and stereoselective desulfonylation of β-tosylhomoallylic alcohols provided a convenient method for the preparation of allylic and homoallylic alcohols. (+/-)-Lavandulol and isolavandulol were synthesized in excellent yields by this method.
STANNANES IN SYNTHESIS: A NEW ROUTE TO 2-SUBSTITUTED-1,3-BUTADIENES VIA STEREOSELECTIVE ALLYLTIN FORMATION UNDER HOMOLYTIC CONDITIONS
Ueno, Yoshio,Sano, Hiroshi,Aoki, Seiichi,Okawara, Makoto
, p. 2675 - 2678 (2007/10/02)
α-(Hydroxymethyl)allyl tolylsulfones reacted with tributyltin hydride in the presence of azobisisobutyronitrile (AIBN) in refluxing benzene to give a allyltin derivatives which subsequently gave 2-substitued-1,3-butadienes upon distillation in good yield.
