79249-74-4

Basic information

• Product Name: 2-hydroxy-5,NN-trimethyl-N-(2-t-butylallyl)anilinium bromide
• CAS NO: 79249-74-4
• Molecular Weight: 328.293
• Mol File: 79249-74-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-hydroxy-5,NN-trimethyl-N-(2-t-butylallyl)anilinium bromide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-hydroxy-5,NN-trimethyl-N-(2-t-butylallyl)anilinium bromide(79249-74-4)
• EPA Substance Registry System: 2-hydroxy-5,NN-trimethyl-N-(2-t-butylallyl)anilinium bromide(79249-74-4)

Safety Data

• Hazardous Substances Data: 79249-74-4(Hazardous Substances Data)

Upstream product

• 3854-52-2 2-(bromomethyl)-3,3-dimethylbut-1-ene 
• 30427-16-8 2-(N,N-dimethylamino)-4-methylphenol 

Downstream Products

• 79249-81-3 N-(2-t-butylallyl)-5,NN-trimethylanilinium-2-olate 

Relevant articles and documents

Base Catalysed Rearrangements involving Ylide Intermediates. Part 13. Further Rearrangements of 2-Oxidoanilinium Ylides

The 2-oxidoanilinium ylides (7) rearrange on heating to give the ethers (10) together with the dienones (8) and the phenols (11) for cases where the aromatic ring has a 5-alkyl substituent or a mixture of the dienones (8) and (12) for cases where the aromatic ring is 3,5-disubstituted.A study of the deuteriated ylides (25) shows that these reactions involve competing concerted and radical-pair processes.The base-catalysed rearrangements of the 2-hydroxy-N-pentadienylanilinium salts (33) give the ethers (34) and the phenols (35): these products result from competing concerted and rearrangements of the ylides (36) corresponding to the salts (33).