79258-04-1Relevant academic research and scientific papers
Synthesis and Reaction of 1,2,4-Trioxanes
Fujisaka, Tomohiro,Miura, Masahiro,Nojima, Masatomo,Kusabayashi, Shigekazu
, p. 1031 - 1039 (2007/10/02)
The peroxides (1a-e) and epoxides (2a-g) in methylene dichloride were treated with tungsten (VI) oxide and then with catalitic amounts of chlorosulphonic acid to give the corresponding 1,2,4-trioxanes (3a-r) in 10-63percent yield.The mode of decomposition of the 1,2,4-trioxanes was studied by treating a number with the following reagents: triethylamine, sodium ethoxide, lithium di-isopropylamide, Grignard and lithium reagents, lithium aluminium hydride, anthrylsodium, triphenylphosphine, and titanium tetrachloride.
