79265-09-1Relevant academic research and scientific papers
PALLADIUM-CATALYZED REARRANGEMENT OF α-CYANOALLYLIC ACETATES APPLICATION TO A NEW SYNTHETIC METHOD FOR FURANS
Mandai, Tadakatsu,Hashio, Susumu,Goto, Jiso,Kawada, Mikio
, p. 2187 - 2190 (2007/10/02)
Various types of α-cyanoallylic acetates were undergone the palladium-catalysed rearrangement to give the γ-acetoxy-α,β-unsaturated nitriles in high yields.These rearranged acetates were conveniently transformed into the furan derivatives often encountered in natural products by the reduction using diisobutylaluminum hydride.
