792965-59-4Relevant academic research and scientific papers
Reactivity of a rhodium(I) complex towards oxygen enhanced by a cyano ligand. Structure of [Rh(CN)(O2)(PPh3)2(XNC)] (XNC = xylyl isocyanide)
C?rcu, Viorel,Fernandes, Manuel A,Carlton, Laurence
, p. 1775 - 1778 (2002)
The complex [Rh(CN)(O2)(PPh3)2(XNC)] (CH2Cl2) has been obtained under ambient conditions from solutions containing trans-[Rh(CN)(PPh3)2(XNC)] upon exposure to air. The compound is unusual in that analogues containing the more strongly electron-donating ligands Cl-, N3- and NCO- (among others) in place of CN- are not formed.
