79384-20-6

Upstream product

• 350255-13-9 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 128573-17-1 (2R,3S,4R)-3,4-Bis-benzyloxy-2-benzyloxymethyl-6-pent-4-enyloxy-tetrahydro-pyran 
• 120316-50-9 Acetic acid (2S,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-phenylselanyl-tetrahydro-pyran-2-yl ester 
• 79384-15-9 (3aR,5R,6S,6aR)-6-((2S,3R,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-phenylselanyl-tetrahydro-pyran-2-yloxy)-5-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole 
• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 

Relevant academic research and scientific papers

Iodonium Ion generated in situ from N-Iodosuccinimide and Trifluoromethanesulphonic acid promotes Direct Linkage of "Disarmed" Pent-4-enyl Glycosides

N-Iodosuccinimide and trifluoromethanesulphonic acid provide a powerful source of iodonium ion which allows "disarmed' pent-4-enyl glycosides that normally respond sluggishly to iodonium dicollidine perchlorate, to react rapidly and to exhibit stereodirec

SELENIUM-MEDIATED GLYCOSIDATIONS: A SELECTIVE SYNTHESIS OF β-2-DEOXYGLYCOSIDES

1,2-Trans diequatorial acetoxy-selenides are selectively prepared from glycals.Their activation by trimethylsilyl trifluoromethanesulfonate in the presence of sugar alcohols followed by reductive deselenation leads to an efficient access to Β-2-deoxyglyco