79417-71-3Relevant academic research and scientific papers
Organoiron Complexes in Organic Synthesis. Part 13. Synthesis of 6,6-Disubstituted Tricarbonyl(cyclohexadienylium)iron Salts, and their Conversion into 4,4-Disubstituted Cyclohexa-2,5-dienones
Pearson, Anthony J.,Ong, Chi Wi
, p. 1614 - 1621 (1981)
Oxidative cyclisation of cyclohexadiene-Fe(CO)3 complexes having a hydroxy-group in the β-position of a 5-exoFe-substituent can be effected with either thallium(III) trifluoroacetate or iron(III) chloride on silica gel.The products were readily converted into the title compounds.
