79421-41-3Relevant academic research and scientific papers
Structure of 8-(4-Acetylphenyl)-1,4-dioxa-8-azaspirodecane: a New Potential Nonlinear Optical Material
Ogawa, Keiichiro,Kaji, Makoto,Kagawa, Hiroyuki,Sagawa, Masakazu,Kakuta, Atsushi
, p. 95 - 97 (1994)
The crystals of the title compound (APDA), C15H19NO3, which belong to a non-centrosymmetric space group Pna21, show significant second harmonic generation efficiency and no absorption for light with a wavelength longer than 400 nm.
Ligand- and Base-Free Copper(II)-Catalyzed C-N Bond Formation: Cross-Coupling Reactions of Organoboron Compounds with Aliphatic Amines and Anilines
Quach, Tan D.,Batey, Robert A.
, p. 4397 - 4400 (2007/10/03)
(Equation presented) A ligandless and base-free Cu-catalyzed protocol for the cross-coupling of arylboronic acids and potassium aryltrifluoroborate salts with primary and secondary aliphatic amines and anilines is described. The process utilizes catalytic copper(II) acetate monohydrate and 4 A molecular sieves in dichloromethane at slightly elevated temperatures under an atmosphere of oxygen. A broad range of functional groups are tolerated on both of the cross-coupling partners.
