79421-94-6Relevant academic research and scientific papers
AN ELECTROCHEMICAL CHLORINATIVE ENE-TYPE REACTION OF ISOPRENOIDS
Torii, Sigeru,Uneyama, Kenji,Nakai, Toshiyuki,Yasuda, Tsuneo
, p. 2291 - 2294 (2007/10/02)
The chlorinative ene-type reaction of isoprenoids (12) has been performed by electrolysis in CH2Cl2-H2O-NaCl system.The reaction provides useful allylic chlorides 2 for terpene synthesis in high yields and is affected strikingly by the nature of halide ions and solvents. dl-Theaspirane 21 was prepared from α-dihydroionol via the electrolysis.
