79424-89-8Relevant academic research and scientific papers
FREE RADICAL CHAIN ELIMINATION REAKTION (ERC1). CONVERSION OF VICINAL DINITRO COMPOUNDS OR β-NITRO SULFONES TO OLEFINS WITH TRIBULYLTIN HYDRIDE
Ono, Noboru,Miyake, Hideyoshi,Tamura, Rui,Hamamoto, Isami,Kaji, Aritsune
, p. 1139 - 1142 (2007/10/02)
Vicinal dinitro compounds (1) or β-nitro sulfones (2) are converted to olefins in good yields on treatment with tributyltin hydride.This elimination proceeds by way of an electron transfer chain mechanism.The elimination from 1 is nonstereospecific and the elimination from 2 is stereospecific.
