79428-82-3Relevant academic research and scientific papers
Palladium-Catalyzed Thiono-Thiolo Allylic Rearrangement of O-Allyl Phosphoro- and Phosphonothionates
Tamaru, Yoshinao,Yoshida, Zen-ichi,Yamada, Yoshimi,Mukai, Kunio,Yoshioka, Hirosuke
, p. 1293 - 1297 (2007/10/02)
The thiono-thiolo allylic rearrangement of O-allyl phosphoro- and phosphonothionates is effected by catalysis with Pd(0).A wide variety of O-allyl thionates (17 kinds) are rearranged selectively to the thermodynamically more stable regio- and stereoisomers via a (?-allyl)palladium intermediate.Thermal rearrangement of α- and γ-methallyl diethyl phosphorothionates is reinvestigated in relation to the regioselectivity observed in the palladium(0) catalysis.
