79445-46-8

Upstream product

• 110-86-1 pyridine 
• 6315-89-5 3,4-dimethoxyaniline 
• 79445-45-7 3-(3,4-Dimethoxyphenyl)pyridine 

Downstream Products

• 1448062-50-7 C₇₂H₄₄B₄F₁₂N₄O₈ 
• 1448062-45-0 C₅₄H₃₃B₃F₉N₃O₆ 
• 1448062-52-9 C₆₈H₄₄B₄F₄N₄O₈ 
• 1448062-47-2 C₅₁H₃₃B₃F₃N₃O₆ 
• 1448062-49-4 C₇₆H₄₀B₄F₂₄N₄O₈ 
• 1448062-43-8 C₅₇H₃₀B₃F₁₈N₃O₆ 

Relevant academic research and scientific papers

Self-assembly of arylboronate esters with pyridyl side chains

Boronate esters that contain N-donor groups are self-complementary structures, which can assemble by means of dative boron-nitrogen bonds to form macrocycles or polymers. Herein, we describe the synthesis of dioxaborinanes and benzodioxaboroles containing pyridyl side chains. In the solid state, the dioxaborinanes were found to exist predominantly as monomers. Upon crystallization, aggregation into one-dimensional polymers was observed, but only for boronate esters that contained electron-withdrawing groups. The more Lewis acidic benzodioxaboroles, on the other hand, were found to form macrocycles both in solution and in the solid state. Copyright