79445-47-9Relevant academic research and scientific papers
Ti(IV)-centered dynamic interconversion between Pd(II), Ti(IV)-containing ring and cage molecules
Hiraoka, Shuichi,Sakata, Yoko,Shionoya, Mitsuhiko
, p. 10058 - 10059 (2008)
Heteronuclear, supramolecular ring and cage complexes have been constructed from a pyridyl catechol ligand, TiO(acac)2, and PdCl2(CH3CN)2. These two complexes are quantitatively interconvertible, in which Ti4+-centered coordination changes take place between a well-known Ti(catecholato)3 and a newly established TiH(catecholato)2(acetylacetonato) structures. The Ti4+-centered structural changes arise from the changes in the component fraction and basicity condition. Copyright
