79465-19-3Relevant academic research and scientific papers
Substitution of Nitrido by the Oxo Group in Reactions of with Multidentate N,O(1-)-donor Chelates. Crystal Structure of
Gerber, Thomas I. A.,Bruwer, Johan,Bandoli, Giuliano,Perils, Joanne,Preez, Jan G. H. du
, p. 2189 - 2192 (1995)
The complex reacts with the potentially bidentate 8-hydroxyquinoline (Hquin) and N-phenylsalicylideneimine (Hpsal), and potentially terdentate ligands di-2-pyridyl ketone and 2,6-bis(hydroxymethyl)pyridine (H2L) to form the products , , > and cis-, respectively.The first three products are identical to those isolated earlier by the reactions of trans- with these ligands, while in the latter product the HL(1-) ligand acts as a bidentate N,O(1-)-donor, spanning one axial (O(1-) trans to Re=O) and one equatorial co-ordination site.These reactions present an alternative synthetic route to monooxorhenium(V) complexes.The complex cis- crystallizes in the orthorhombic space group P212121 with cell parameters a = 10.019(3), b = 12.457(6), c = 19.53(1) Angstroem, U = 2436.5 Angstroem3, Z = 4, R = 0.059 and R' = 0.074 for 1330 reflections with F0 > 4?(F0).
