79499-04-0

Basic information

• Product Name: (3aS,5S,7aS)-4,4,7a-Trimethyl-5-phenylselanyl-hexahydro-benzofuran-2-one
• Synonyms: (3aS,5S,7aS)-4,4,7a-Trimethyl-5-phenylselanyl-hexahydro-benzofuran-2-one
• CAS NO: 79499-04-0
• Molecular Weight: 337.32
• Mol File: 79499-04-0.mol

Chemical Properties

• CAS DataBase Reference: (3aS,5S,7aS)-4,4,7a-Trimethyl-5-phenylselanyl-hexahydro-benzofuran-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (3aS,5S,7aS)-4,4,7a-Trimethyl-5-phenylselanyl-hexahydro-benzofuran-2-one(79499-04-0)
• EPA Substance Registry System: (3aS,5S,7aS)-4,4,7a-Trimethyl-5-phenylselanyl-hexahydro-benzofuran-2-one(79499-04-0)

Safety Data

• Hazardous Substances Data: 79499-04-0(Hazardous Substances Data)

Upstream product

• 5707-04-0 Phenylselenyl chloride 
• 459-85-8 (E)-4,8-dimethylnona-3,7-dienoic acid 
• 79499-01-7 (4R,5S)-5-Methyl-5-(4-methyl-pent-3-enyl)-4-phenylselanyl-dihydro-furan-2-one 

Downstream Products

• 87164-34-9 (3R,3aS,6R,7aS)-4,4,7a-Trimethyl-3-phenylselanyl-6-(tetrahydro-pyran-2-yloxy)-hexahydro-benzofuran-2-one 
• 1133-03-5 (+/-)-loliolide 
• 1666-13-3 diphenyl diselenide 
• 16778-27-1 (+/-)-(3aα,7aα)-4,4-7a-trimethyl-3a,4,5,6,7,7a-hexahydrobenzofuran-2(3H)-one 

Relevant articles and documents

SYNTHESE DU (+/-) LOLIOLIDE PAR POLYCYCLISATION DE L'ACIDE HOMOGERANIQUE.

A new synthesis of (+/-) loliolide was achieved from pure homogeranic acid in a stereospecific fashion.The intermediate ethylenic lactone 6 was converted to the racemate of lol

CYCLISATION DE COMPOSES ETHYLENIQUES PAR ASSISTANCE D'IONS SELENIRANIUMS

Acid-catalyzed cyclization of ethylenic selenolactone 3 derived from homogeranic acid 1 affords one bicyclic lactone 5.This intramolecular rearrangement is induced by a seleniranium ion.