79528-51-1

Basic information

• Product Name: Phenyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-1-thio-beta-D-glucopyranoside
• Synonyms: Phenyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-1-thio-beta-D-glucopyranoside
• CAS NO: 79528-51-1
• Molecular Weight: 489.549
• Mol File: 79528-51-1.mol

Chemical Properties

• CAS DataBase Reference: Phenyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-1-thio-beta-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: Phenyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-1-thio-beta-D-glucopyranoside(79528-51-1)
• EPA Substance Registry System: Phenyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-1-thio-beta-D-glucopyranoside(79528-51-1)

Safety Data

• Hazardous Substances Data: 79528-51-1(Hazardous Substances Data)

Upstream product

• 31505-45-0 2-deoxy-2-phthalimido-D-glucopyranose 
• 85-44-9 phthalic anhydride 
• 79528-49-7 phenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 17314-33-9 tributyltin phenyl sulfide 
• 4551-15-9 phenylthiotrimethylsilane 
• 10022-13-6 1,3,4,6-tetra-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranose 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 136882-36-5 2-((2S,3R,4R,5S,6R)-4,5-Dihydroxy-6-hydroxymethyl-2-phenylsulfanyl-tetrahydro-pyran-3-yl)-isoindole-1,3-dione 

Downstream Products

• 148705-04-8 Acetic acid (2R,3S,4R,5R,6S)-2-acetoxymethyl-5-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)-6-phenylsulfanyl-4-((2R,3R,4S,5S,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl ester 
• 148705-05-9 4-nitrophenyl O-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1-3)-O-(4,6-di-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1-3)-2,4,6-tri-O-acetyl-β-D-galactopyranoside 
• 79528-55-5 phenyl 6-O-benzoyl-3-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 79528-54-4 phenyl 6-O-acetyl-3-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 79528-53-3 phenyl 3-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 148705-03-7 phenyl 4,6-benzylidene-2-deoxy-3-O-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 141342-83-8 phenyl 6-O-benzyl-2-deoxy-2-phthalimido-1-thio-1-deoxy-β-D-glucopyranoside 
• 79528-52-2 2-((4aR,6S,7R,8R,8aS)-8-Benzyloxy-2-phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-isoindole-1,3-dione 
• 141342-85-0 Phenyl O-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1->4)-O-<(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-(1->3)>-6-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 141342-84-9 Phenyl O-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1->4)-6-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 

Relevant articles and documents

BIFUNCTIONAL COMPOUND AND ITS USE IN IMMUNOTHERAPY

The invention relates to a bifunctional compound that is, on one side, an agonist of the TLR4 and, on the other side, an important inhibitor of the PSMA. Said compound is useful in immunotherapy for the treatment and/or prevention of prostate cancer. Therefore, the invention also relates to the use of the compound and to the pharmaceutical composition comprising it.

Copper(II) triflate: A versatile catalyst for the one-pot preparation of orthogonally protected glycosides

The development of general and expedient methodologies for the preparation of orthogonally protected glycoside building blocks is essential for the efficient synthesis of complex oligosaccharides. Herein, we describe a new approach that uses copper(II) triflate as a versatile catalyst for the one-pot preparation of orthogonal protected thio- and O-glycosides from the corresponding unprotected counterparts. The conditions are mild, easy to handle and applicable to two and three one-pot tandem transformations, which include arylidene acetalation, esterification, regioselective reductive acetal ring opening, glycosylation and silylation processes. Copyright

Iodine-catalyzed one-pot acetalation-esterification reaction for the preparation of orthogonally protected glycosides

An iodine-catalyzed one-pot tandem acetalation-esterification reaction of thio- and O-glycosides has been developed providing a fast and mild route to orthogonally protected glycosides ready to be used as building blocks in glycosylation reactions.

Synthesis of oligosaccharides containing the X-antigenic trisaccharide (α-L-Fucp-(1-->3)-4)-β-D-GlcpNAc) at their nonreducing ends

The "armed" methyl 2,3,4-tri-O-benzyl-1-thio-β-L-fucopyranoside was reacted with "disarmed" phenyl O-(tetra-O-acetyl-β-D-galactopyranosyl)-(1-->4)-6-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside in the presence of CuBr2-Bu4NBr complex to give