795311-52-3

Upstream product

• 696-62-8 para-iodoanisole 
• 321155-39-9 dimethyl(2-pyridinyl)(vinyl)silane 

Downstream Products

• 795311-32-9 4-[(Z)-2-(Dimethyl-pyridin-2-yl-silanyl)-1-(4-methoxy-phenyl)-vinyl]-benzonitrile 
• 795311-31-8 1-{4-[(Z)-2-(Dimethyl-pyridin-2-yl-silanyl)-1-(4-methoxy-phenyl)-vinyl]-phenyl}-ethanone 
• 851286-83-4 C₃₈H₄₀N₂O₂Si₂ 
• 795311-33-0 2-{[(Z)-2-(4-Methoxy-phenyl)-2-(4-nitro-phenyl)-vinyl]-dimethyl-silanyl}-pyridine 

Relevant academic research and scientific papers

Triarylethene-based extended π-systems: Programmable synthesis and photophysical properties

(Chemical Equation Presented) On the basis of an efficient Pd-catalyzed triarylation to a vinylsilane platform, four types of structurally well-defined triarylethene-based extended π-systems have been prepared very rapidly. From a compound library constructed by the present method, it was possible to find a number of interesting fluorescent materials, as well as interesting fluorescent properties such as aggregation-induced enhanced emission. A useful method for the rapid synthesis and property evaluation has also been developed.

Stereoselective synthesis of multisubstituted butadienes through directed Mizoroki-Heck reaction and homocoupling reaction of vinyl(2-pyridyl)silane

(Chemical Equation Presented) We have developed the homocoupling reaction of alkenyl(2-pyridyl)silanes mediated by Cul and CsF, in which the strong directing effect of the 2-pyridyl group was observed. The homocoupling reaction was successfully integrated with the Mizoroki-Heck reaction of vinyl(2-pyridyl)-silane with aryl halides, enabling a rapid and stereoselective synthesis of multisubstituted butadienes. From a relatively small compound library, it was possible to detect a number of fluorescent butadienes with a wide range of fluorescence color variations (blue to reddish-orange).