795313-80-3Relevant academic research and scientific papers
Racemic but tropos (chirally flexible) BIPHEP ligands for Rh(I)-complexes: Highly enantioselective ene-type cyclization of 1,6-enynes
Mikami, Koichi,Kataoka, Shohei,Yusa, Yukinori,Aikawa, Kohsuke
, p. 3699 - 3701 (2004)
(Chemical Equation Presented) The tropos (chirally flexible) or atropos (chirally rigid) nature of BIPHEP-Rh complexes at room temperature critically depends on the amines complexed. The aliphatic DPEN complex is atropos, whereas the aromatic DABN complex
