79534-38-6Relevant academic research and scientific papers
4:1 Lewis base adducts of palladium bis(hexafluoroacetylacetonate). The structure of (4-ClC5H4N)4Pd(C5HF 6O2)2
Siedle,Pignolet
, p. 135 - 141 (1982)
Palladium bis(hexafluoroacetylacetonate), Pd(F6acac)2, reacts with a wide variety of Lewis bases to form 4:1 adducts of the type (L4Pd2)(F6acac)2 where L includes (CH3)2/su
Reactions of metallodithiolate ligand with palladium dichloride bearing monophosphine or diphosphine
Sheng, Yu-Dong,Yu, Xiao-Yong,Liu, Xu-Feng
, p. 215 - 220 (2017)
Reaction of metallodithiolate ligand Ni(bme-dach?) [bme-dach??=?N,N′-bis(mercaptoethyl)-1,4-diazacyclohexane] with Pd[P(4-C6H4CH3)3]2Cl2 in the presence of NH4PF6 yielded a heterobimetallic complex {Ni(bme-dach?)Pd[P(4-C6H4CH3)3]2}[PF6]2 (1) in 43% yield. However, reaction of Ni(bme-dach?) with Pd(dppm)Cl2 [dppm?=?1,1-bis(diphenylphosphino)methane] resulted in the formation of a mononuclear Pd complex [Pd(dppm)2][PF6]2 (2) via dissociation between Pd–P bonds. Moreover, reaction of Ni(bme-dach?) with Pd(dppv)Cl2 [dppv?=?cis-1,2-bis(diphenylphosphino)ethylene] in the presence of NH4PF6 afforded an expected product [Ni(bme-dach?)Pd(dppv)][PF6]2 (3) in 80% yield as well as an unexpected product {Ni(bme-dach?)[Pd(dppv)Cl]2}[PF6]2 (4) as a byproduct. The new complexes 1 and 3 were characterized by elemental analysis, 1H NMR and 31P{1H} NMR spectroscopy. In addition, the structures of the complexes 1–4 were confirmed by single crystal X-ray diffraction analysis.
