79547-73-2Relevant academic research and scientific papers
Simulation mathematique appliquee a l'elaboration des mecanismes des re actions chimiques intervenant lors de l'electrolyse de la parabenzoquinone monochlorimine sur electrode de platine
Bonastre, J.,Castetbon, A.,Andrieu, X.
, p. 283 - 289 (2007/10/02)
Electrolysis of highly concentrated solutions of quinone-monochlorimine on platinum electrode produces various compounds.The whole reaction mechanism cannot be completely elucidated by interpretation of electrochemical and spectroscopic results.Kinetic data can be analysed by computerized integration of a non linear first order differential equation system.Complete reaction models and reduction mechanisms are obtained from these results.
MECANISMES DE REDUCTION ELECTROCHIMIQUE DES QUINONES MONO ET DICHLORIMINE SUR PLATINE. ETUDE ET STRUCTURE DES COMPOSES OBTENUS LORS DE COULOMETRIES A FORTE CONCENTRATION
Bonastre, J.,Castetbon, A.,Andrieu, X.
, p. 145 - 152 (2007/10/02)
In this work, electrochemical reduction of quinone mono and dichlorimine was investigated on platinum cathodes.The first product produces paraaminophenol and the second produces paraphenylenediamine.Chemical reactions occur when the concentration of initial product is higher than E-4 M.Reaction between quinone monochlorimine and its ultimate reduction product occurs when concentrated solution are electrolysed on a platinum cathode.In this work, the nature and the structure of the reaction products were eluciated by physicochemical methods.An approach of the reaction mechanism is proposed.
