79562-32-6Relevant academic research and scientific papers
Asymmetric catalysis. Mechanism of asymmetric catalytic intramolecular hydrosilation
Bergens, Steven H.,Noheda, Pedro,Whelan, John,Bosnich
, p. 2128 - 2135 (2007/10/02)
The mechanism of asymmetric catalytic intramolecular hydrosilation using [Rh(diphosphine)]+ catalysts has been investigated by the use of specifically labeled deuterated substrates. It is concluded that oxidative addition of the silicon hydride
Specific Hydromagnesiation of Prop-2-ynylic Alcohols. A Simple and Specific Route to Terpenoids
Sato, Fumie,Ishikawa, Hiroaki,Watanabe, Hiroshi,Miyake, Tooru,Sato, Masao
, p. 718 - 720 (2007/10/02)
Hydromagnesiation of prop-2-ynylic alcohols proceeds with stereo- and regio-specificity, affording, under mild conditions, the alkenylmagnesium halides (5) in almost quantitative yields, thus providing a novel and simple route to terpenoids.
