79562-48-4

Upstream product

• 591-51-5 phenyllithium 
• 79562-43-9 10-methoxytricyclo<5.3.1.0^2,6>undeca-3,9-dien-8-one 
• 79562-47-3 10-methoxytricyclo<5.3.1.0^2,6>undeca-4,9-dien-8-one 

Downstream Products

• 82968-74-9 C₁₇H₁₆O 
• 82968-73-8 C₁₇H₁₆O 
• 108957-30-8 (3aS,3bR,6aS,7aR)-6-Phenyl-3a,3b,4,6a,7,7a-hexahydro-cyclopenta[a]pentalen-1-one 

Relevant academic research and scientific papers

Synthesis and Photolysis of Tricyclo2,6>undeca-3,9-dien-8-ones and -4,9-dien-8-ones. Formation of Novel Trishomocubanones

A series of 10-substituted tricyclo2,6>undeca-3,9-dien-8-ones (6) and the 4,9-dien-8-one isomers (7) were synthesized and photolyzed.Upon irradiation, whereas most of the derivatives underwent photocyclization to give the correspo

INTRAMOLECULAR PHOTOCHEMICAL REACTIONS OF RIGID DIENONES. PREPARATION AND PHOTOLYSIS OF 10-SUBSTITUTED TRICYCLO 2,6> UNDECA-3,9-DIEN-8-ONES AND -4,9-DIEN-8-ONES

A series of the title compounds (R=OMe, H, Me, Ph) were prepared and photochemical behaviors of these compounds were examined.Although most of the substrates underwent intramolecular cycloaddition to give novel trishomocubanes upon irradiation, the phenyl derivative of Δ4 isomer gave a product via competing allylic hydrogen abstraction, as well as the cyclization product.