79563-01-2

Upstream product

• 123643-47-0 [(2R,3R)-3-(2,6,6-Trimethyl-cyclohex-1-enylmethyl)-oxiranyl]-methanol 
• 688753-82-4 C₂₀H₂₈N₂O₂S 
• 80707-20-6 [(E)-4-(2,6,6-Trimethyl-cyclohex-1-enyl)-but-2-enylsulfanyl]-benzene 
• 123643-45-8 ethyl 4-(2',6',6'-trimethyl-1'-cyclohexenyl)-2-butenoate 
• 123643-46-9 4-(2',6',6'-trimethyl-1'-cyclohexenyl)-2-butenol 
• 86558-54-5 2-((E)-2-Methoxy-vinyl)-1,3,3-trimethyl-cyclohexene 
• 432-25-7 2,6,6-trimethylcyclohex-1-enecarbaldehyde 
• 472-66-2 (2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde 
• 123643-48-1 (2S,3R)-2-Iodomethyl-3-(2,6,6-trimethyl-cyclohex-1-enylmethyl)-oxirane 

Relevant academic research and scientific papers

Enantiocontrolled synthesis of quaternary carbon centers via anionic oxy-cope rearrengement: An efficient synthesis of (+)-dihydromayurone

(+)-Dihydromayurone (1) was enantioselectively synthesized from β-cyclocitral (7). The key step in the synthesis involved anionic oxy-Cope of allylic alcohol 6 to aldehyde 5. Efficient transfer of chirality from the secondary allylic alcohol center to the quaternary carbon center was observed vai chairlike transition state with the equatorial oxyanionic bond.

A NEW APPROACH TO REGIOCONTROLLED ENONE TRANSPOSITIONS BASED ON THE FACILE CONVERSION OF α,β-ENONE TOSYLHYDRAZONES TO THE TRANSPOSED ALLYLIC SULFIDES

A new, facile method for the conversion of α,β-enone tosylhydrazones to the transposed allylic sulfides is described which combines sulfenylation of the hydrazone dianions with hydride reduction of the α'-sulfenylated hydrazones.This novel route to allyli