79566-25-9

Upstream product

• 122-78-1 phenylacetaldehyde 
• 622-37-7 Phenyl azide 
• 62-53-3 aniline 
• 5883-81-8 2-anilinoacetophenone 
• 88091-16-1 N-(1-phenylethylidene)aniline 
• 79566-23-7 3-Benzyl-5-<(hydroxy)(phenyl)amino>-2,4-diphenylisoxazolidin 
• 70-11-1 α-bromoacetophenone 
• 859157-94-1 1,3,4-triphenyl-2,5-dihydro-1H-pyrrole 
• 82937-44-8 2,3-diphenylbutane-1,4-diylidenebis(aniline N-oxide) 

Relevant academic research and scientific papers

Synthetic method of 3-aryl substituted pyrrole compound

The invention discloses a synthetic method of a 3-aryl substituted pyrrole compound, and belongs to the technical field of organic synthesis. The method includes the steps: adding N-substituted piperidine 1 into a solvent; performing heating reaction in o

Visible-Light-Driven Synthesis of 1,3,4-Trisubstituted Pyrroles from Aryl Azides

The synthesis of 1,3,4-trisubstituted pyrroles via visible-light mediated photoredox catalyzed condensation of arylazides and aldehydes has been reported herein. The methodology avoids the use of stoichiometric oxidants and provides the corresponding N-co

Electrochemical oxidative annulation of amines and aldehydes or ketones to synthesize polysubstituted pyrroles

A general and practical protocol to synthesize polysubstituted pyrroles has been established by electrooxidative annulation of amines and aldehydes or ketones. In an undivided cell, arylacetaldehydes and primary amines can participate in this transformati

Copper-Catalyzed Aerobic Oxidation and Oxygenation of Anilines and Acetaldehydes with Dioxygen for the Concise Synthesis of 2-Aroylquinolines

A concise and efficient aerobic oxidation and oxygenation approach for the construction of 2-aroylquinolines has been developed through copper-catalyzed annulation of anilines, acetaldehydes, and dioxygen. 2,2,6,6-Tetramethylpiperidine-1-oxyl was employed to direct the selectivity toward the desired 2-aroyl products. Molecular oxygen was used in this transformation as an environmentally benign source of oxygen.

Manganese (III) acetate mediated synthesis of polysubstituted pyrroles under solvent-free ball milling

Under solvent-free ball milling conditions, a simple and mild method was developed for efficient synthesis of 2,5-dimethyl-3,4-dicarboxylate-pyrroles and N-substituted 3,4-diphenylpyrroles via condensation-annulation of amines with acetoacetate and 2-phen

I2-catalyzed synthesis of substituted pyrroles from α-amino carbonyl compounds and aldehydes

A direct method for the synthesis of 1,3,4-triarylpyrroles was achieved easily from cyclization of α-amino carbonyl compounds and aldehydes catalyzed by I2. Various substituted groups can be employed, and this reaction can proceed smoothly in moderate to good yields.

One-pot AgOAc-mediated synthesis of polysubstituted pyrroles from primary amines and aldehydes: Application to the total synthesis of purpurone

A simple and efficient method for the synthesis of 1,3,4-trisubstituted or 3,4-disubstituted pyrroles has been developed. The reaction represents the first time that pyrroles are synthesized directly from readily available aldehydes and amines (anilines)

A new approach to the preparation of 1,3,4-triarylpyrroles

A class of 1,3,4-triaryl-2,5-dihydropyrroles were synthesized using the McMurry coupling reaction as the key step. The non-catalytic photoconversion of 1,3,4-triaryl-2,5-dihydropyrroles furnished 1,3,4-triarylpyrroles in good yields (63-89%). It was found

Study on photochromism of diarylethenes with a 2,5-dihydropyrrole bridging unit: A convenient preparation of 3,4-diarylpyrroles from 3,4-diaryl-2,5- dihydropyrroles

Symmetric and nonsymmetric diarylethenes with a 2,5-dihydropyrrole bridging unit have been prepared, and the photochromic properties are investigated. Both symmetric and nonsymmetric diarylethenes with 2,5-dihydropyrrole bridging units undergo reversible ring-opening and ring-closing photoisomerization reactions in nonpolar solvents with UV/vis light, and some of them exhibit good fatigue resistance and no marked degradation detected after 10 cycles via an on/off switch. In polar solvents, however, photochromic diarylethenes with 2,5-dihydropyrrole bridging units produce 3,4-diarylpyrrole derivatives instead of the ring-closing isomer of diarylethenes with UV light irradiation. A class of N-substituted 3,4-diphenylethenes with 2,5-dihydropyrrole bridging units were prepared and used as templates to investigate the conversion reactions. The mechanism of photoconversion of 3,4-diaryl-2,5-dihydropyrroles to 3,4-diarylpyrroles was explored as well.

Dinitrones from C-Benzyl Nitrones

N,N'-Dialkyl- and diaryl-dinitrones of the 2,3-diphenylbutanediylidenebisamine N,N'-dioxide (3) are shown to be intermediates in the spontaneous conversion of C-benzyl nitrones (1) into the diphenylpyrroles (4) or 2,3-diphenylprop-2-en-1-al (5).The proces