79587-79-4Relevant articles and documents
THERMOLYSIS AND PHOTOLYSIS OF S-SUBSTITUTED 2,5-DIPHENYL-1,4-DITHIINS
Kobayashi, Keiji,Mutai, Kiyoshi
, p. 43 - 52 (2007/10/02)
The thermolysis of 2,5-diphenyl-1,4-dithiin-1-oxide (4) in the liquid phase induced rearrangement to 2-formyl-2,4-diphenyl-1,3-dithiole (7) and extrusion of sulfur oxide to give 2,4-diphenylthiophene (2a) as well as deoxygenation to 2,5-diphenyl-1,4-dithi
SKELETAL REARRANGEMENT OF 2,5-DIARYL-1,4-DITHIIN-1-OXIDES INDUCED BY HYDROCHLORIC ACID
Kobayashi, Keiji,Mutai, Kiyoshi
, p. 1105 - 1108 (2007/10/02)
Treatment of 2,5-diphenyl-1,4-dithiin-1-oxide with hydrochloric acid in dioxane caused a novel skeletal rearrangement to give 2-benzoyl-4-phenyl-1,3-dithiole together with the deoxygenation products.The reaction with gaseous hydrogen chloride in methanol