796038-73-8

Upstream product

• 104-87-0 4-methyl-benzaldehyde 
• 196929-78-9 (R)-2-methylpropane-2-sulfinamide 

Downstream Products

• 865354-95-6 2-Methyl-propane-2-sulfinic acid ((1S,2R)-2-cyclohexyl-2-hydroxy-1-p-tolyl-ethyl)-amide 
• 1508278-93-0 C₂₅H₄₅NO₄SSi 
• 1426585-72-9 pinacol (R)-((R)-tert-butanesulfinamido)(4-methylphenyl)methylboronate 
• 1298087-71-4 C₂₉H₄₂N₂O₅SSi 
• 911321-10-3 (1R,2S)-2-Amino-1-cyclohexyl-2-p-tolyl-ethanol 
• 911321-09-0 (1S,2R)-1-Amino-3-ethyl-1-p-tolyl-pentan-2-ol 
• 911321-08-9 (1S,2R)-1-Amino-3-methyl-1-p-tolyl-butan-2-ol 
• 865354-96-7 2-Methyl-propane-2-sulfinic acid ((1S,2R)-3-ethyl-2-hydroxy-1-p-tolyl-pentyl)-amide 

Relevant academic research and scientific papers

Highly diastereoselective reactions of 2-lithiated indoles with chiral N-tert-butanesulfinyl aldimines for the synthesis of chiral (2-indolyl) methanamine derivatives

Nucleophilic addition reactions of 2-lithiated N-phenylsulfonylindoles with (R)-N-tert-butanesulfinyl aldimines provided chiral (2-indolyl) methanamine derivatives in moderate to good yields (up to 100%) with excellent diastereoselectivities (>99:1), in which no additional Lewis acids were required.

Diastereoselective and enantioselective Rh(I)-catalyzed additions of arylboronic acids to N-tert-butanesulfinyl and N-diphenylphosphinoyl aldimines

Two new Rh(I)-catalyzed methods for the synthesis of chiral α-branched amines via addition of arylboronic acids to N-tert-butanesulfinyl and N-diphenylphosphinoyl imines have been developed. The syntheses are more functional group tolerant than alternativ