79606-82-9

Upstream product

• 119-61-9 benzophenone 
• 77903-42-5 2-tert-Butyl-2-trimethylsilanyloxy-cyclopropanecarboxylic acid methyl ester 

Downstream Products

• 79606-83-0 5-tert-Butyl-tetrahydro-5-methoxy-2,2-diphenyl-3-furancarbonsaeure-methylester 
• 102536-82-3 5-tert-Butyl-5-cyano-2,2-diphenyl-tetrahydro-furan-3-carboxylic acid methyl ester 
• 79606-84-1 5-tert-Butyl-2,3-dihydro-2,2-diphenyl-3-furancarbonsaeure-methylester 
• 102536-81-2 5-Allyl-5-tert-butyl-2,2-diphenyl-tetrahydro-furan-3-carboxylic acid methyl ester 

Relevant academic research and scientific papers

C-C-Bond Formation by Lewis Acid Induced Cyclopropane Ring Cleavage - New Routes to Highly Substituted Furan(one) Derivatives

Activation by stoichiometric quantities of titanium tetrachloride allows addition of ketones to methyl 2-siloxycyclopropanecarboxylates 1, which affords hydroxylalkylation products 3/4 under ring cleavage.There are, however, restrictions regarding the cyc

LEWIS-ACID-PROMOTED ADDITIONS OF CARBONYL COMPOUNDS TO DONOR-ACCEPTOR SUBSTITUTED CYCLOPROPANES: A NEW SYNTHESIS OF 2,3-DIHYDROFURANE DERIVATIVES

Methyl 2,3-dihydrofurane-3-carboxylates are synthesized from siloxycyclopropaneesters and ketones in the presence of TiCl4 with good yields.