79646-43-8

Upstream product

• 131750-34-0 Methanesulfonic acid (S)-cyclohexyl-((2S,3S)-3-cyclohexyl-oxiranyl)-methyl ester 
• 931-48-6 2-cyclohexylacetylene 
• 2043-61-0 cyclohexanecarbaldehyde 
• 79605-63-3 (E)-1,3-dicyclohexyl-2-propen-1-ol 
• 79646-50-7 (S)-Cyclohexyl-((2R,3S)-3-cyclohexyl-oxiranyl)-methanol 

Relevant academic research and scientific papers

Catalytic Asymmetric Synthesis of Secondary (E)-Allyl Alcohols from Acetylenes and Aldehydes via (1-Alkenyl)zinc Intermediates

Hydroboration of aliphatic 1-alkynes with freshly prepared dicyclohexylborane (1 mol-equiv., hexane), treatment of the resulting boranes 5 with Et2Zn or Me2Zn (1.05 mol-equiv.) followed by addition of (-)-3-exo-(dimethylamino)isoborneol (DA

Telluride-mediated stereospecific conversion of racemic E-allylic alcohols to homochiral Z-allylic alcohols; transposition of primary and secondary allylic alcohols via glycidol derivatives

Racemic trans-secondary allylic alcohols can be converted to homochiral cis-secondary allylic alcohols by means of a telluride-mediated transposition reaction applied to the homochiral glycidol obtained from a Sharpless kinetic resolution. (+)-Linalool is obtained in>95% enantiomeric excess from geraniol, an example of a transposition of a primary allylic alcohol to a homochiral tertiary alcohol.