79676-05-4Relevant articles and documents
REACTION OF N-BENZYLIDENEPERCHLOROVINYLAMINE WITH PRIMARY AND SECONDARY AMINES
Drach, B. S.,Popovich, T. P.,Kisilenko, A. A.,Kalinin, V. N.,Soifer, G. B.,Gordeev, A. D.
, p. 1093 - 1099 (2007/10/02)
When N-benzylideneperchlorovinylamine (C6H5CH=NCCl=CCl2) is reacted with highly basic secondary amines, a rearrangement occurs already under mild conditions, and substituted amino nitriles with the general formula C6H5CH(NR2)CCl2CN, whose structure was rigorously proved by chemical and spectral methods, form unexpectedly.Primary amines react differently with N-benzylideneperchlorovinylamine, and the main reaction products are N-benzylidenealkylamines and dichloroacetonitrile.
