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Highly Efficient Method for Ethylenic or Acetylenic Ketones via Fragmentation of Hydroxy Vinyl Selenones
Shimizu, Makoto,Ando, Ryoichi,Kuwajima, Isao
, p. 5246 - 5248 (1981)
Treatment of cyclic 3-hydroxyvinyl selenones with bases at room temperature lea2s to the formation of ethylenic or acetylenic ketones in good yields via 1,4-fragmentaion, where phenylselenonyl group behaves as an excellent nucleofuge.
