79681-46-2Relevant academic research and scientific papers
Reactions of 3-Hydroxyvinyl Selenones with Alkoxides. Oxetane Formation and Fragmentation Reactions
Shimizu, Makoto,Ando, Ryoichi,Kuwajima, Isao
, p. 1230 - 1238 (2007/10/02)
3-Hydroxyvinyl phenyl selenones are prepared and their behavior as conjugate addition acceptors has been investigated.As a result, a selenonyl group has been found to activate the C=C bond for conjugate addition of nucleophiles and further to behave as an
Highly Efficient Method for Ethylenic or Acetylenic Ketones via Fragmentation of Hydroxy Vinyl Selenones
Shimizu, Makoto,Ando, Ryoichi,Kuwajima, Isao
, p. 5246 - 5248 (2007/10/02)
Treatment of cyclic 3-hydroxyvinyl selenones with bases at room temperature lea2s to the formation of ethylenic or acetylenic ketones in good yields via 1,4-fragmentaion, where phenylselenonyl group behaves as an excellent nucleofuge.
