79685-70-4Relevant articles and documents
BICYCLIC PEROXIDES FROM A 1,4-DIAZEPINE
Ramakrishnan, V. T.,Boyer, Joseph H.
, p. 1345 - 1351 (2007/10/02)
An adduct, 3,4-dicyano-1,6-dimethyl-2,5-diaza-7,8-dioxabicyclonon-3-ene, was obtained from 2,3-dicyano-5,7-dimethyl-6H-1,4-diazepine and hydrogen peroxide in the presence of alkali or a tertiary amine.It was dehydrogenated by iodobenzene diacetate into 3,4-dicyano-1,6-dimethyl-2,5-diaza-7,8-dioxabicyclonona-2,4-diene; further oxidation by m-chloroperbenzoic acid gave 4,5-dicyano-1,8-dimethyl-2,7-diaza-3,6,9,10-tetraoxatetracyclo2,405,7>undecane.