797-71-7Relevant articles and documents
From Mesomorphic Phosphine Oxide to Clustomesogens Containing Molybdenum and Tungsten Octahedral Cluster Cores
C?rcu, Viorel,Molard, Yann,Amela-Cortes, Maria,Bentaleb, Ahmed,Barois, Philippe,Dorcet, Vincent,Cordier, Stéphane
, p. 10921 - 10925 (2015)
New clustomesogens (i.e., metal atom clusters containing liquid crystalline (LC) materials) have been obtained by grafting neutral cyanobiphenyl (CB)- or cholesteryl-containing tailor-made dendritic mesomorphic triphenylphosphine oxide ligands on luminesc
Self-assembly of Amphiphilic Porphyrins To Construct Nanoparticles for Highly Efficient Photodynamic Therapy
Jiang, Meiyu,Wu, Jiasheng,Liu, Weimin,Ren, Haohui,Zhang, Wenjun,Lee, Chun-Sing,Wang, Pengfei
, p. 11195 - 11204 (2021/06/01)
Hydrophobic photosensitizers greatly affect cell permeability and enrichment in tumors, but they cannot be used directly for clinical applications because they always aggregate in water, preventing their circulation in the blood and accumulation in tumor
Preparation method of high-reproducibility tris(4-carboxybiphenyl)phosphine
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, (2020/11/23)
The invention relates to the technical field of organic methodology, and relates to a preparation method of high-reproducibility tris(4-carboxybiphenyl)phosphine. The preparation method comprises thefollowing steps: reacting a hydroxyl-substituted phosphorus precursor with p-toluenesulfonyl chloride to form a compound, and carrying out a Suzuki coupling reaction on the compound to obtain anmethylester compound of a pentavalent phosphorus ligand; and carrying out chlorosilane reduction and hydrolysis to obtain the high-purity tris(4-carboxylbiphenyl)phosphine. The preparation method of tris(4-carboxyl biphenyl)phosphine has high reproducibility, and avoids using of butyl lithium and other high-risk organic reagents to synthesize brominated precursors. The preparation method of tris(4-carboxyl biphenyl)phosphine is high in yield and suitable for large-scale production.
Multifunctional crosslinking agent, crosslinked polymer, and method of making same
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, (2019/06/27)
A multifunctional crosslinking agent, a crosslinked polymer, and a method of making the same are disclosed. The multifunctional crosslinking agent, which may be used to crosslink amine-terminated polyamides, polyimides, or poly(amide-imide)s, includes thr