797035-75-7

Upstream product

• 143-33-9 sodium cyanide 
• 797035-74-6 (2R,3R,4R,5R,6S)-2-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-6-iodomethyl-4-(4-methoxy-benzyloxy)-3,5-dimethyl-tetrahydro-pyran 
• 797035-72-4 (2R,3R,4R,5R,6S)-2-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-6-iodomethyl-3,5-dimethyl-tetrahydro-pyran-4-ol 

Downstream Products

• 881838-57-9 [6-(2-{2-[6-(9-bromo-6-methoxy-3-methyl-1-triisopropylsilanyloxy-nona-2,4,8-trienyl)-2,4-dimethoxy-tetrahydro-pyran-2-ylmethyl]-oxazol-4-yl}-1-methyl-vinyl)-4-(4-methoxy-benzyloxy)-3,5-dimethyl-tetrahydro-pyran-2-yl]-acetaldehyde 
• 797035-78-0 (2R,3R,4S,5S,6R)-6-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-4-(4-methoxy-benzyloxy)-3,5-dimethyl-tetrahydro-pyran-2-carbaldehyde 
• 797035-79-1 1-[(2R,3R,4S,5S,6R)-6-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-4-(4-methoxy-benzyloxy)-3,5-dimethyl-tetrahydro-pyran-2-yl]-ethanone 
• 797035-77-9 tert-Butyl-{2-[(2R,3S,4S,5R,6R)-6-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-4-(4-methoxy-benzyloxy)-3,5-dimethyl-tetrahydro-pyran-2-yl]-ethoxy}-diphenyl-silane 
• 797035-69-9 4-{(E)-2-[(2R,3R,4S,5S,6R)-6-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-4-(4-methoxy-benzyloxy)-3,5-dimethyl-tetrahydro-pyran-2-yl]-propenyl}-2-methyl-oxazole 
• 797035-82-6 4-[6-(4-{2-[6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4-(4-methoxy-benzyloxy)-3,5-dimethyl-tetrahydro-pyran-2-yl]-propenyl}-oxazol-2-ylmethyl)-4,6-dimethoxy-tetrahydro-pyran-2-yl]-2-methyl-4-triisopropylsilanyloxy-but-2-enal 
• 797035-81-5 4-[6-(4-{2-[6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4-(4-methoxy-benzyloxy)-3,5-dimethyl-tetrahydro-pyran-2-yl]-propenyl}-oxazol-2-ylmethyl)-4,6-dimethoxy-tetrahydro-pyran-2-yl]-2-methyl-4-triisopropylsilanyloxy-but-2-en-1-ol 
• 797035-80-4 C₆₆H₁₀₃NO₁₀Si₃ 
• 797035-67-7 C₆₇H₉₈BrNO₁₀Si₂ 
• 797035-76-8 2-[(2R,3S,4S,5R,6R)-6-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-4-(4-methoxy-benzyloxy)-3,5-dimethyl-tetrahydro-pyran-2-yl]-ethanol 

Relevant academic research and scientific papers

Total synthesis of phorboxazole B

An efficient and highly convergent total synthesis of the potent antitumor agent phorboxazole B has been achieved. The synthetic strategy of this synthesis features: 1) a highly efficient substrate-controlled hydrogenation to construct the functionalized

Toward the total synthesis of phorboxazole B: An efficient synthesis of the C20-C46 segment

(Chemical Equation Presented) An efficient synthesis of the C20-C46 segment of phorboxazole B is described. The key steps involved Hg(OAc) 2/I2-induced cyclization to construct the cis-tetrahydropyran moiety, the coupling of the meta