79722-71-7

Basic information

• Product Name: 2-<(2,2-dimethyl-1-phenylpropylidene)amino>-2,4,4-trimethylpentane
• CAS NO: 79722-71-7
• Molecular Weight: 273.462
• Mol File: 79722-71-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-<(2,2-dimethyl-1-phenylpropylidene)amino>-2,4,4-trimethylpentane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-<(2,2-dimethyl-1-phenylpropylidene)amino>-2,4,4-trimethylpentane(79722-71-7)
• EPA Substance Registry System: 2-<(2,2-dimethyl-1-phenylpropylidene)amino>-2,4,4-trimethylpentane(79722-71-7)

Safety Data

• Hazardous Substances Data: 79722-71-7(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 13987-63-8 N-Methylen-1,1,3,3-tetramethylbutylamin 
• 594-19-4 tert.-butyl lithium 

Downstream Products

• 938-16-9 2,2-dimethylpropiophenone 

Relevant articles and documents

Metallo Aldimines. 3. Coupling of Lithium Aldimines with Aryl, Vinyl, and Acetylenic Halides

tert-Butyllithium aldimine, an acyl anion equivalent derived from 1,1,3,3-tetramethylbutyl isocyanide (TMBI) and tert-butyllithium, couples with aryl, vinyl, and acetylenic halides to give the corresponding ketimine which upon hydrolysis affords the corresponding ketones.These coupling reactions appear to result from halogen-metal exchange followed by addition-elimination to give the observed products.