79751-94-3Relevant articles and documents
Iminodimagnesium Reagents. Condensation Reaction with Ketones. Direct Preparation of Anils and a Hydrazone of Xanthone
Okubo, Masao,Hayashi, Saeko,Matsunaga, Mayumi,Uematsu, Yumiko
, p. 2337 - 2340 (1981)
The condensation reaction of ketones with iminodimagnesium reagents (RN(MgBr)2) derived from various primary amines as well as 1,1-disubstituted hydrazines was investigated.A-Arylimines and 1-methyl-1-phenylhydrazones of diaryl ketones were prepared, thei
The thermal and photolytic decomposition of 9-aryl-9-xanthenyl azides to 11-aryldibenzo[b,f][1,4] oxazepines
Coombes, Philip,Goosen, Andre,Taljaard, Benjamin
, p. 559 - 563 (2007/10/02)
In contrast to the different ratios of products obtained in the thermal decomposition of some 9-aryl-9-xanthenyl azides, it was found that photolysis afforded the same product ratio. The mechanism of these reactions is discussed in terms of intermediates as well as conformational and electronic effects in the transition states.